DNA photocleavage in anaerobic conditions by a Ru(ii) complex: a new mechanism.
نویسندگان
چکیده
[Ru(bpy)2(py-SO3)](+) (bpy = 2,2'-bipyridine and py-SO3 = pyridine-2-sulfonate) was found to undergo py-SO3 dissociation upon visible light irradiation (≥470 nm) via Ru-O homolysis, producing reactive free radical species, and is thus able to not only photobind but also photocleave DNA in hypoxic conditions.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 2 شماره
صفحات -
تاریخ انتشار 2015